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Phosphorus — Purple Phosphorus

015Reactive nonmetal · Group 15 · Period 3

Phosphorus

Phosphorus (P) is element 15, a reactive nonmetal in the p-block — group 15, period 3. It is a solid at room temperature with 3 electron shells (2, 8, 5) and an atomic mass of 30.9737619985 u.

Atomic mass
30.97 u
Phase · STP
solid
Melting
Boiling
Electronegativity
2.19
Density
1.823 g/cm³

Photograph — Jurii, CC BY 3.0 <https://creativecommons.org/licenses/by/3.0>, via Wikimedia Commons, source: https://images-of-elements.com/phosphorus.php

Identity

Atomic number
15
Standard atomic weight
30.97 u
Category
Reactive nonmetal
Group
15 · Pnictogens
Period
3
Block
p-block
Oxidation states
+5, +3, -3

Physical properties

Melting point
Boiling point
Density
1.823 g/cm³
Molar heat capacity
23.824 J/(mol·K)
Atomic radius
180 pm
Electron affinity
72.037 kJ/mol

Atomic structure

P
15protons
16neutrons
15electrons
5valence e⁻
Noble-gas notation
[Ne] 3s2 3p3
Full configuration
1s2 2s2 2p6 3s2 3p3
Electrons per shell
2, 8, 5

Periodic trends

Where Phosphorus ranks across all 118 elements.

Electronegativity2.19
Ionization energy1011.8 kJ/mol
Electron affinity72.037 kJ/mol
Density1.823 g/cm³
Atomic radius180 pm

Ionization energies

Energy to remove each successive electron (kJ/mol).

1.0k
1
1.9k
2
2.9k
3
5.0k
4
6.3k
5
21.3k
6
25.4k
7
29.9k
8
35.9k
9
41.0k
10

Successive ionization energies (kJ/mol, log scale).

Discovery

Discovered
1669
Discovered by
Hennig Brand
Named by
Appearance
colourless, waxy white, yellow, scarlet, red, violet, black

Position in the table